Spaceport Structures and Materials
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Research and Technology 2002
 
Electrochemical Analysis of Chloride Rinse Agents on Aircraft Alloys
 

The purpose of this project is to analyze the effects of several chloride rinse agents (CRA’s) on aircraft alloys using electrochemical techniques. This analysis is being carried out in parallel with the “Army Corrosion Retardant Additive Testing” that is being conducted by NASA and Dynacs at the Beach Corrosion Test Site at Kennedy Space Center.


The study analyzes the corrosion behavior of eight different metal alloys (listed in the table) immersed in six different solutions and in demineralized water. The solutions include four commercially available chloride rinse agents along with seawater and 3.5-percent sodium chloride (NaCl). The seawater and the demineralized water are being included as controls. The 3.5-percent NaCl solution was included because it is often used as a substitute for seawater and because of the availability of data on the corrosion behavior of materials in this environment. The commercially available rinse agents are being diluted in accordance with the manufacturers’ specifications.


The study being conducted includes measurement of the opencircuit potential for an hour, linear polarization, potentiodynamic scans (PDS’s), and cyclic polarization scans. The series of experiments is being conducted at different immersion times to monitor the performance of the metal with immersion time. An electrochemical flat cell designed to expose 1 square centimeter of metal to the rinse (electrolyte) is being used in the investigation. The data obtained will be analyzed to determine the corrosion rate, the susceptibility of the metal to pitting corrosion, and the magnitude of recovery.

 

Electrochemical Instruments and Laboratory Setup

Electrochemical Instruments and Laboratory Setup

Contacts: Dr. L.M. Calle (Luz.Calle-1@ksc.nasa.gov), YA-C2-T, (321) 867-3278; and L.G. MacDowell, YA-C2-T, (321) 867-4550
Participating Organization: Dynacs Inc. (R.D. Vinje and J.J. Curran)

Metals, Rinses, and Techniques Used in the Electrochemical Analysis ofChloride Rinse Agents on Aircraft Alloys
Metal Alloys
Rinses*
Electrochemical
Techniques*
Aluminum
Al 2024 T3
Rinse 1
Corrosion Potential
Al 7075 T6
Rinse 2
Linear Polarization
Steel Alloy
4340
Rinse 3
Potentiodynamic Scan
High-Strength Steel
PH13-8Mo
Rinse 4
Cyclic Polarization
C 250
Seawater
 
AM 350
Demineralized Water
 
Titanium Alloy
Ti-6Al-4V
3.5% NaCl
 
Magnesium Alloy
AZ31B-H24
   
* All rinses and electrochemical techniques are used on each metal.

 

Potentiodynamic Scans Recorded During Preliminary ExperimentsPotentiodynamic Scans Recorded During Preliminary Experiments

Potentiodynamic Scans Recorded During Preliminary Experiments

     
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